화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.136, No.1-2, 31-36, 1997
Electrostatic model for substituent and solvent effects on organic acids
On the bases of experimental results from gas phase and electrostatic theory a modified thermodynamic model for substituent and solvent effects on organic acids has been derived. It is found that the present model is quantitatively and simultaneously consistent with the experimental results obtained from gas phase, aqueous solution and mixed solvents such as ethanol-H2O.