Journal of Crystal Growth, Vol.310, No.12, 3004-3008, 2008
Compositional analysis of In-rich InGaN layers grown on GaN templates by metalorganic chemical vapor deposition
In-rich InGaN layers were successfully grown on GaN templates by metalorganic chemical vapor deposition. In incorporation in InGaN layer was enhanced by decreasing the growth temperature, and In-rich InGaN layer with In content higher than 70% was obtained below 670 degrees C. Especially, double peaks from In-rich InGaN grown at 640 degrees C appeared in X-ray diffraction pattern and photoluminescence (PL). The further investigation of strain status of InGaN layers by reciprocal space mapping (RSM) clarified that In-rich InGaN layers were fully relaxed and consisted of InGaN alloys of two different In contents of 82% and 97%, respectively. As a result, we confirmed that compositional inhomogeneity which is mainly reported in Ga-rich InGaN layer could exist in In-rich InGaN layer higher than 80%. We also investigated In incorporation behavior in InGaN at low temperature (640 degrees C). In content in InGaN layer was found to be controlled by just changing input gas phase mole fraction (TMIn/(TMGa+TMIn)) at low growth temperature and a linear relationship was observed between In content in InGaN layers and gas phase mole fraction. (c) 2008 Elsevier B.V. All rights reserved.
Keywords:X-ray diffraction;metalorganic chemical vapor deposition;nitrides;semiconducting ternary compounds