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Fluid Phase Equilibria, Vol.140, No.1-2, 233-244, 1997
Viscometric and volumetric studies on binary mixtures of 1,2-dichloroethane and chlorinated methanes or their binary equimolar mixtures at 303.15 K
Excess viscosities, eta(E) and molar excess volumes V-E were obtained for binary mixtures of 1,2-dichloroethane and chlorinated methanes and for pseudobinary mixtures of 1,2-dichloroethane and equimolar binary mixtures from chlorinated methanes at 303.15 K. The chlorinated methanes include carbon tetrachloride, chloroform and dichloromethane. Grunberg-Nissan interaction parameter d and interaction energy for flow of activation W-vis were also presented. The relationship between the eta(E)'s and the V-E's has been quantitively considered using Singh's equations. The excess viscosities for all the systems are negative over the entire compositions. There are specific interactions between 1,2-dichloroethane and chlorinated methanes, but the specific interactions are not strong. The interactions of 1,2-dichloroethane with chlorinated methanes decrease in the order : chloroform > dichloromethane > carbon tetrachloride. 'Pseudochloroform' has been defined by us for the first time as the equimolar mixture of dichloromethane and carbon tetrachloride.
Keywords:EXCESS VOLUMES;METHYLENE-CHLORIDE;CYCLOHEXANE;THERMODYNAMICS;VISCOSITIES;CHLOROFORM;BEHAVIOR;ACETONE