The two-equation porous medium model has been widely employed for modeling the flow-through monolithic catalytic converter. In this model, the interfacial heat and mass transfer coefficients have been usually obtained using the asymptotic Nusselt and Sherwood numbers with some suitable assumptions. However, previously it seemed that there existed some misunderstanding in adopting these Nusselt and Sherwood numbers. Up to now, the Nusselt number based on the fluid bulk mean temperature has been used for determining the interfacial heat and mass transfer coefficients. However, the mass and energy balance formulations in the two-equation model indicate that the Nusselt number should be evaluated based on the fluid mean temperature instead of the fluid bulk mean temperature. Therefore, in this study, to correctly model the heat and mass transfer coefficients, the Nusselt number based on the fluid mean temperature was newly obtained for the square and circular cross-sections under two different thermal boundary conditions (i.e., constant heat flux and constant temperature at the wall). in order to do that, the present study employed the numerical as well as analytical method. (C) 2008 Elsevier Ltd. All rights reserved.