In this paper, transient responses of a porous urea particle bed subject to a step change in the inlet temperature or humidity for a forced convective air flow through the particle bed are investigated to determine the convective heat and mass transfer coefficients inversely by comparing the measured time constant with the predicted characteristic time constant, which is a function of the convection coefficients and Reynolds number. The experimental results show, that although both the time constants for temperature and humidity step changes are dependent on Reynolds number, the temperature response time constant (35-1300s) is much larger than the humidity response time constant (4-25s) for the Reynolds number range of 300-5. The surface adsorption of water vapor is very rapid but the absorption inside the porous urea particle is slowed by a very low internal effective diffusion coefficient within the particles whereas the very low Biot number for heat transfer in the particles implies a complete thermal interaction with the air flow throughout each particle and a much larger time constant. Empirical correlations of the Chilton-Colburn j-factor and Nusselt number versus Reynolds number are compared with the correlations of other researchers. These new correlations, which include an uncertainty analysis, imply much lower convective coefficients than those reported previously in the literature. (C) 2009 Elsevier Ltd. All rights reserved.