Inorganic Chemistry, Vol.47, No.18, 8159-8166, 2008
Infrared spectra, structure, and bonding of the GeH3-CrH, HGe MoH3, and HGe WH3 molecules in solid neon and argon
Laser ablated chromium, molybdenum, and tungsten atoms react with germane during condensation in excess noble gases. The chromium reaction stopped at the germyl metal hydride, molybdenum gave some hydride but mostly germylidyne, and tungsten reacted spontaneously to give only the germylidyne species. These molecules were identified by isotopic shifts, density-functional theory product energy and frequency calculations, and comparison to the analogous methane and silane reaction products. Effective bond orders for the HGe MoH3 and HGe WH3 molecules are 2.82 and 2.87 using the B3LYP density functional, and are slightly lower than their silicon and carbon analogues. Our calculated Ge M triple bond lengths for these simple trihydride complexes are 0.05 to 0.10 angstrom shorter than those measured for larger group 6 organometallic complexes.