Inorganic Chemistry, Vol.47, No.21, 9739-9741, 2008
1,2,4-Diazaphospholide Complexes of Samarium(III)
A series of 1,2,4-diazaphospholide (dp(-)) samarium complexes with a variety of coordination modes were prepared via the metathesis reaction of SmCl3(THF)(3) and potassium 3,5-disubstituted 1,2,4-diazaphospholide or by the reaction of Sm[N(SiMe3)(2)](3) and 3,5-diphenyl-1,2,4-diazaphosphole.