Fluid Phase Equilibria, Vol.149, No.1-2, 139-145, 1998
The influence of the temperature on the liquid-liquid equilibrium of the ternary system 1-butanol-1-propanol-water
Liquid-liquid equilibrium data for the ternary system l-butanol-l-propanol-water have been determined experimentally at 25, 50, 85 and 95 degrees C. The results obtained have been correlated simultaneously by the UNIQUAC method obtaining two sets of interaction parameters : one of them independent of the temperature and the other with a linear dependence. Both sets of parameters fit the experimental results well which is an improvement on using parameters depending of the temperature of 15%.