New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers

Liu L; Ferdov S; Coelho C; Kong Y; Mafra L; Li JP; Dong JX; Kolitsch U; Ferreira RAS; Tillmanns E; Rocha J; Lin Z

Inorganic Chemistry, Vol.48, No.11, 4598-4600, 2009

Liu L, Ferdov S, Coelho C, Kong Y, Mafra L, Li JP, Dong JX, Kolitsch U, Ferreira RAS, Tillmanns E, Rocha J, Lin Z

A novel layered zinc phosphate, [N2C6H12](2)[Zn7H3(HPO4-x)(5)(PO4)(3)] H2O, with unique 10-membered-ring ellipsoidal channels running perpendicularly to ladder-shaped tetrahedral layers, has been synthesized ionothermally via in situ generation of 1,4-diazabicyclo[2.2.2] octane.