Electroconductive Porous Coordination Polymer Cu[Cu(pdt)(2)] Composed of Donor and Acceptor Building Units

Takaishi S; Hosoda M; Kajiwara T; Miyasaka H; Yamashita M; Nakanishi Y; Kitagawa Y; Yamaguchi K; Kobayashi A; Kitagawa H

Inorganic Chemistry, Vol.48, No.19, 9048-9050, 2009

Takaishi S, Hosoda M, Kajiwara T, Miyasaka H, Yamashita M, Nakanishi Y, Kitagawa Y, Yamaguchi K, Kobayashi A, Kitagawa H

We synthesized a new porous coordination polymer Cu[Cu(pdt)(2)], which shows relatively high electrical conductivity (6 x 10(-4) S cm(-1) at 300 K) by the introduction of electron donors and acceptors as building units. This compound is applicable as a porous electrode with high power density. In addition, this compound forms a triangular spin lattice and shows spin frustration.