We prepared several Ni,Na-mordenites by ion-exchange of commercial Na-mordenite in the liquid phase under microwaves irradiation and by conventional heating for comparison. After one exchange at 333 K, similar amounts of exchanged Ni2+ (around 47%) were achieved with and without microwaves but faster under microwave irradiation. Making an intermediate thermal treatment under microwaves between two exchanges, also made under microwaves, the exchanged Ni2+ increased up to 84%. Interestingly, microwaves strongly affect the acidity of the exchanged samples since they showed the appearance of new weak acid sites, which increased as longer the microwaves treatment was (NH3-TPD). This agrees with the higher amounts of Lewis acid centres observed by adsorbed pyridine FTIR for these samples. These new sites were not observed for the conventional exchanged sample. From these results, we believe that microwaves could interact with nickel cations inducing the formation of weak-acid hydrolised nickel species [Ni(OH)](+) for the microwaved samples. These acid characterization results were confirmed by testing several of these Ni,Na-mordenites in two reactions catalysed by different acid sites. (C) 2009 Elsevier B.V. All rights reserved.