Journal of Industrial and Engineering Chemistry, Vol.15, No.5, 618-623, September, 2009
The development of a fully integrated micro-channel fuel processor using low temperature co-fired ceramic (LTCC)
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A fully integrated micro-channel fuel processor system consisting of vaporizer, steam reformer, heat exchanger and preferential CO oxidation (PROX) was developed using low temperature co-fired ceramic (LTCC). To fabricate a compact all-in-one system, each substrate was stacked to build a multilayered type fuel processor. A CuO/ZnO/Al2O3 catalyst and Pt-based catalyst prepared by wet impregnation were deposited inside the micro-channel of steam reformer and PROX, respectively. The performance of the fully integrated micro-channel reformer wasmeasured at various conditions such as the ratio of the feed flow rate, the ratio of H2O/CH3OH and the operating temperature of the reactor. In parallel with the experiments, 3-D fluid dynamics simulation (Fluent) was conducted to verify the micro-reformer performance. The fully integrated micro-channel reformer has the dimensions of W: 130 mm × D:50 mm× H: 3 mm. The fuel processor produced the gas composition of 71% H2 and 25% CO2, and more than 93% of methanol conversion was achieved at 300 ℃ and 2 cm3/h of the feed flow rate when CO concentration was maintained below 100 ppm by PROX.
- Marino F, Descorme C, Duprez D, Appl. Catal. B: Environ., 54(1), 59 (2004)
- Rosso L, Galletti C, Saracco G, Garrone E, Specchia V, Appl. Catal. B: Environ., 48(3), 195 (2004)
- Agrell J, Birgersson H, Boutonnet M, J. Power Sources, 106(1-2), 249 (2002)
- Jung MJ, Kim JW, Im JS, Park SJ, Lee YS, J. Ind. Eng. Chem., 15(3), 410 (2009)
- Park GG, Yim SD, Youn YG, Lee WY, Kim CS, Seo DJ, Eguchi K, J. Power Sources, 145(2), 702 (2005)
- Kim S, Hong I, J. Ind. Eng. Chem., 14(3), 357 (2008)
- Shin Y, Kim O, Hong JC, Oh JH, Kim WJ, Haam S, Chung CH, Int. J. Hydrogen Energy, 31, 1925 (2006)
- Hrovat M, Belavic D, Kita J, Cilensek J, Golonka L, Dziedzic A, J. Euro. Ceram. Soc., 25, 3443 (2005)
- Kwon OJ, Hwang SM, Ahn JG, Kim JJ, J. Power Sources, 156(2), 253 (2006)
- Lindstrom B, Agrell J, Pettersson LJ, Chem. Eng. J., 93(1), 91 (2003)
- Choi Y, Stenger HG, J. Power Sources, 124(2), 432 (2003)
- Choi Y, Stenger HG, J. Power Sources, 129(2), 246 (2004)
- Bravo J, Karim A, Conant T, Lopez G, Datye A, Chem. Eng. J., 11, 113 (2004)
- Karim A, Bravo J, Gorm D, Conant T, Datye A, Catal. Today, 110(1-2), 86 (2005)
- Park GG, Yim SD, Yoon YG, Kirn CS, Seo DJ, Eguchi K, Catal. Today, 110(1-2), 108 (2005)
- Takeda K, Baba A, Hishinuma Y, Chikahisa T, JSAE Rev., 23, 183 (2002)
- Park GG, Seo DJ, Park SH, Yoon YG, Kim CS, Yoon WL, Chem. Eng. J., 101(1-3), 87 (2004)
- Pan L, Wang S, Int. J. Hydrogen Energy, 30, 973 (2005)
- Echigo M, Shinke N, Takami S, Tabata T, J. Power Sources, 132, 25 (2004)
- Zhou S, Yuan Z, Wang S, Int. J. Hydrogen Energy, 31, 924 (2006)