Although technologies have been developed for the clean, efficient use of coal for power generation, there exist some barriers to their adoption and implementation. These technologies are essentially based upon coal gasification, which also provides a route for the synthesis of chemicals and fuels from coal. An overview is given of commercial experience of power generation by integrated gasification combined-cycle, and chemicals production. Against this background, a "Pioneer Plant＇＇ concept is described that can facilitate the introduction of advanced technologies through the co-production of power and added-value products in a single plant. The term ＇＇Pioneer＇＇ in this context reflects the nature of a first-of-a-kind plant that integrates existing technologies from the utility and petrochemical industries. The potential technical, economic, and greenhouse gas reduction advantages that can be realized through the development of an integrated, multiplex operation are discussed.