Applied Surface Science, Vol.255, No.18, 8003-8009, 2009
Effects of growth temperature modulated by HCl flow rate on the surface and crystal qualities of thick GaN by HVPE
We studied the influence of the growth temperature and HCl flow rate on the morphological evolution of crack-free thick GaN films by using a home-made horizontal hydride vapor phase epitaxy on sapphire substrates. Optical differencemicroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and cathodoluminescence (CL) were carried out to reveal the surface property of the GaN epilayer. It was found that the higher growth temperature is a key factor to obtain mirror, colorless and flat GaN surface. However, this key effect of temperature was modulated by HCl flow rate (HCl > 15 sccm). The surface RMS roughness was reduced from 206 to 2.51 nm for 10 mu m x 10 mu m scan area when GaN was grown at 1070 degrees C with HCl flow rate up to 30 sccm. These samples also reduced their (0 0 0 2) FWHM result from 1000 to 300 arcsec and showed a strong near-band-edge peak in CL spectra. Results indicated that growth temperature influence growth velocities on different crystalline planes, which will lead to the different morphologies obtained. High growth temperature can improve the lateral growth rate of vertical {1 1 - 2 0} facets and reduce the vertical growth rate of top {0 0 0 1} facet combined with higher HCl flow rate, which leads to completely coalescence of surface. (C) 2009 Elsevier B.V. All rights reserved.
Keywords:Thick GaN;Growth temperature;HCl flow rate;Hydride vapor phase epitaxy;Surface and crystal qualities