Measurement of adsorption characteristics of alumina and activated carbon using a quartz crystal resonator with i-butane

Byoung Chul Kim; Takuji Yamamoto; Yoon Sup Byun; Young Han Kim

Korean Journal of Chemical Engineering, Vol.27, No.1, 328-333, January, 2010

DOI10.1007/s11814-009-0345-x Export Citation

Measurement of adsorption characteristics of alumina and activated carbon using a quartz crystal resonator with i-butane

Byoung Chul Kim , Takuji Yamamoto¹, Yoon Sup Byun², and Young Han Kim^†

Department of Chemical Engineering, Dong-A University, Busan 604-714, Korea
¹National Institute of Advanced Industrial Science and Technology, Ibaraki 305-8565, Japan
²Department of Chemical Engineering, Pusan National University, Busan 609-735 Korea

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A new device for measuring the pore characteristics of adsorbents is developed for fast measurement and convenient sample handling. The proposed device utilizes a quartz crystal resonator capable of detecting the change of mass loading in nanogram scale. The measured material is coated on the electrode surface of the resonator, and the change of resonant frequency of the resonator at different pressures of adsorbate gas is converted into the adsorbed amount used in the computation of the adsorption surface area and pore size. For the performance evaluation of the device, alumina and activated carbon are tested with the adsorbate, i-butane. The experimental results show that the proposed device gives comparable measurements with some deviation to the reference values of the adsorption characteristics. It is proved that the device is relatively simple and requires short measurement time and the mild condition of sample handling.

Keywords:Quartz Crystal Resonator;Adsorbent;Adsorption Characteristic;i-Butane Adsorption

[References]

Krutyeva M, Grinberg F, Furtado F, Galvosas P, Karger J, Silvestre-Albero A, Sepulveda-Escribano A, Silvestre-Albero J, Rodriguez-Reinoso F, Micropor. Mesopor. Mater., 120, 91 (2009)
Bourgeois A, Turcant Y, Walsh C, Defranoux C, Adsorpt. J. Int. Adsorpt. Soc., 14, 457 (2008)
Makowski W, Chmielarz L, Kustrowski P, Micropor. Mesopor. Mater., 120, 257 (2009)
Tanchoux N, Trens P, Maldonado D, Di Renzo F, Fajula F, Coll. Surf. A: Physicochem. Eng. Aspects, 246, 1 (2004)
Buttry DA, Ward MD, Chem. Rev., 92, 1355 (1992)
Choi KJ, Kim YH, Chang SM, Egawa A, Muramatsu H, Anal. Chim. Acta, 386, 229 (1999)
Kim BC, Kim YH, Japanese J. Appl. Phys., 46, 7490 (2007)
Kim BC, Kang HW, Kim YH, Korean J. Chem. Eng., 23(5), 789 (2006)
Kasai N, Sugimoto I, Nakamura M, Katoh T, Biosensors & Bioelectronics, 14, 533 (1999)
Nakamura K, Nakamoto T, Moriizumi T, Sens. Actuators B: Chem., 69, 295 (2000)
Sheng HJ, Shih JS, Anal. Chim. Acta, 350, 109 (1997)
Abbas MN, Moustafa GA, Mitrovics J, Gopel W, Anal. Chim. Acta, 393, 67 (1999)
Kasai N, Sugimoto I, Nakamura M, Sens. Actuators B: Chem., 65, 114 (2000)
Kim JM, Chang SM, Suda Y, Muramatsu H, Sens. Actuators A: Phys., 72, 140 (1999)
Kim YH, Choi KJ, Sens. Actuators B, 87, 196 (2002)
Park YM, Kim YH, Yamamoto T, Sens. Actuators B: Chem., 125, 468 (2007)

[Referenced By]

[Related Articles]

[1] Krutyeva M, Grinberg F, Furtado F, Galvosas P, Karger J, Silvestre-Albero A, Sepulveda-Escribano A, Silvestre-Albero J, Rodriguez-Reinoso F, Micropor. Mesopor. Mater., 120, 91 (2009)

[2] Bourgeois A, Turcant Y, Walsh C, Defranoux C, Adsorpt. J. Int. Adsorpt. Soc., 14, 457 (2008)

[3] Makowski W, Chmielarz L, Kustrowski P, Micropor. Mesopor. Mater., 120, 257 (2009)

[4] Tanchoux N, Trens P, Maldonado D, Di Renzo F, Fajula F, Coll. Surf. A: Physicochem. Eng. Aspects, 246, 1 (2004)

[5] Buttry DA, Ward MD, Chem. Rev., 92, 1355 (1992)

[6] Choi KJ, Kim YH, Chang SM, Egawa A, Muramatsu H, Anal. Chim. Acta, 386, 229 (1999)

[7] Kim BC, Kim YH, Japanese J. Appl. Phys., 46, 7490 (2007)

[8] Kim BC, Kang HW, Kim YH, Korean J. Chem. Eng., 23(5), 789 (2006)

[9] Kasai N, Sugimoto I, Nakamura M, Katoh T, Biosensors & Bioelectronics, 14, 533 (1999)

[10] Nakamura K, Nakamoto T, Moriizumi T, Sens. Actuators B: Chem., 69, 295 (2000)

[11] Sheng HJ, Shih JS, Anal. Chim. Acta, 350, 109 (1997)

[12] Abbas MN, Moustafa GA, Mitrovics J, Gopel W, Anal. Chim. Acta, 393, 67 (1999)

[13] Kasai N, Sugimoto I, Nakamura M, Sens. Actuators B: Chem., 65, 114 (2000)

[14] Kim JM, Chang SM, Suda Y, Muramatsu H, Sens. Actuators A: Phys., 72, 140 (1999)

[15] Kim YH, Choi KJ, Sens. Actuators B, 87, 196 (2002)

[16] Park YM, Kim YH, Yamamoto T, Sens. Actuators B: Chem., 125, 468 (2007)