Control of the non-adiabatic photodissociation dynamics of CH2BrCl into CH2Br + Cl or CH2Cl + Br has been achieved using a driving few-cycle IR laser pulse followed by a control UV pulse. Employing two-dimensional time-dependent wave packet propagations on a three-state diabatic model we show that the branching ratio leading to the dissociation of the stronger bond ( C-Cl) can be increased by an order of magnitude. (C) 2008 Elsevier B.V. All rights reserved.