화학공학소재연구정보센터
Chemical Physics Letters, Vol.483, No.1-3, 62-66, 2009
Short pulse-induced solute migration in an organic solution at two temperatures
To explain the experimental observation that a short pulse with energy exceeding a threshold can induce the outward solute migration in an ethanolic solution of chloroaluminum phthalocyanine, we have modeled each solute molecule as an oscillator confined within a potential well formed by the attractive forces of neighboring solvent molecules. In this report, we further infer that the threshold increases with a decreasing solution temperature. This inference is verified by measuring the energy thresholds for a 19 picosecond pulse to induce the outward solute migration in this solution at two temperatures of 288 K and 293 K. (C) 2009 Elsevier B.V. All rights reserved.