Chemistry Letters, Vol.37, No.7, 678-679, 2008
Two neutral open-framework metal phosphites with ten-ring channels constructed by three-, four-, and five-connected centers
Neutral open-structured metal phosphites of Al and In are hydrothermally synthesized; they are structural analogues that constructed by HPO3 and MO6 groups with intersecting eight- and 10-ring channels. The two metal sites serve as four- and five-connected centers, respectively, with the rest oxygen atoms belonging to the coordinated water molecules.