Three-dimensional Nickel(II) Heptacyanomolybdate(III)-based Magnet

Tomono K; Tsunobuchi Y; Nakabayashi K; Kosaka W; Matsuda T; Ohkoshi S

Chemistry Letters, Vol.38, No.8, 810-811, 2009

DOI10.1246/cl.2009.810 Export Citation

Three-dimensional Nickel(II) Heptacyanomolybdate(III)-based Magnet

Tomono K, Tsunobuchi Y, Nakabayashi K, Kosaka W, Matsuda T, Ohkoshi S

Herein we prepared a three-dimensional nickel heptacyanomolybdate-based magnet, K0.6Ni1.7II[Mo-III(CN)(7)]center dot 5.5H(2)O center dot 0.5CH(3)OH. This compound exhibited magnetic ordering with a Curie temperature of 28K due to ferromagnetic coupling between magnetic spins on Ni-II (S = 1) and Mo-III (S = 1/2).