화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.17, No.12, 987-994, December, 2009
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Hybrid Nanocomposites of Palladium Nanoparticles Having POSS and MWNTs via Ionic Interactions
Jong-hwan Jeon, Jung-hyurk Lim, and Kyung-min Kim†
  • Department of Polymer Science and Engineering, Chungju National University, Chungbuk 380-702, Korea
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Palladium nanoparticles having cubic silsesquioxanes (POSS) (Pd-POSS) were produced by the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-NH3+) in methanol at room temperature. Functionalized multiwalled carbon nanotubes (MWNT-COOH) were prepared by acid treatment of pristine MWNTs. The hybrid nanocomposites of Pd-POSS and MWNT-COOH (Pd-MWNT nanocomposites) were synthesized by self-assembly method via ionic interaction between positively charged Pd-POSS and negatively charged MWNT-COO-. The spherical aggregates of Pd-POSS with a diameter of 40-60 nm were well attached to the surfaces of MWNT-COOH on Silicon wafer. The composition, structure, and surface morphology of Pd-MWNT nanocomposites were studied by UV-vis spectrophotometer, energy dispersive spectrum (EDX), scanning electron microscopy (SEM), and atomic force microscope (AFM).
Keywords:palladium nanoparticles;multiwalled carbon nanotube;self-assembly;hybrid nanocomposites;surface modification
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