Carbon dioxide is one of the global warming gases. Utilization of a sustainable energy is one of the effective technologies for the mitigation Of CO2 accumulation in the atmosphere. If renewable energy can be used for methane synthesis, H-2 is converted to methane by reducing CO2. We investigated the conversion of CO2 to CH4 using a novel hollow-fiber membrane biofilm reactor. We have converted CO2 to CH4 with autotrophic methanogens Using CO2 and H-2. All the gases were diffused into water through the membrane without bubbles. We have Successfully operated the Hf-MBfR for stable methane production from CO2 and H2 under Continuous operations for 60-70 days at acidic and neutral pH. The methane ratio of the gas produced depended on the pH condition and reached about 60% at neutral pH and 80-90%, at acidic pH. The Produced methane contents were 751 mL day(-1) on average from 20 to 58 days at neutral pH and 135 mL day(-1) on average from 36 to 43 days, 247 mL day(-1) on average from 44 to 70 days at acidic pH. At neutral pH, during the operating periods, acetic acid was continuously produced to 4000-7000 mg/L so that produced methane was considered to have been produced by hydrogenotrophic methanogens and acetoclastic methanogens. At acidic pH, during the initial operating periods, pH was maintained to 5.9-6.6 so that acetic acid was produced by acetogens. After adjusting to less than pH 5.5, however, it was decreased. At the same time, the methane contents produced were considered to have increased by acetoclastic methanogens.