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Electrochemical and Solid State Letters, Vol.12, No.4, H95-H97, 2009
Characteristics and Cleaning of Dry-Etching-Damaged Layer of Amorphous Oxide Thin-Film Transistor
The damage of an amorphous Ga2O3-In2O3-ZnO (a-GIZO) thin-film transistor (TFT) due to dry etching was removed by wet-cleaning treatment and characterized in terms of electrical performance. The damaged channel layer by dry etch had lower chemical bonding energy than that of the as-deposited layer due to physical bombardment. It seems to be oxygen deficient and to have a reduction of metal cation. The existence of a damaged layer in the a-GIZO TFT tends to significantly deteriorate threshold voltage, subthreshold swing, and off-current. With the wet-cleaning treatment, however, the damaged layer was successfully removed, thereby revealing significantly recovered electrical performances. X-ray photoelectron spectroscopy, Auger electron spectroscopy, and transmission electron spectroscopy analysis support the evidences such as channel-layer composition, chemical bonding structure, and cross structure.
Keywords:Auger electron spectra;cleaning;etching;gallium compounds;II-VI semiconductors;indium compounds;thin film transistors;transmission electron microscopy;wide band gap semiconductors;X-ray photoelectron spectra;zinc compounds