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Electrochemical and Solid State Letters, Vol.12, No.7, G34-G36, 2009
Remote Plasma ALD of Platinum and Platinum Oxide Films
Platinum and platinum oxide films were deposited by remote plasma atomic layer deposition (ALD) from the combination of (methylcyclopentadienyl)trimethylplatinum (MeCpPtMe3) precursor and O-2 plasma. A short O-2 plasma exposure (0.5 s) resulted in low resistivity (15 mu Omega cm), high density (21 g/cm(3)), cubic Pt films, whereas a longer O-2 plasma exposure (5 s) resulted in semiconductive PtO2 films. In situ spectroscopic ellipsometry studies revealed no significant nucleation delay, different from the thermal ALD process with O-2 gas which was used as a benchmark. A broad temperature window (100-300 degrees C) for remote plasma ALD of Pt and PtO2 was demonstrated.
Keywords:atomic layer deposition;electrical resistivity;metallic thin films;plasma materials processing;platinum;platinum compounds;semiconductor growth;semiconductor thin films