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Electrochemical and Solid State Letters, Vol.12, No.11, H408-H411, 2009
Low Temperature PE-TEOS Oxide Bonding Assisted by a Thin Layer of High-kappa Dielectric
The bond strength of plasma-enhanced tetraethyl-orthosilicate (PE-TEOS) oxide, bonded and annealed at low temperatures (300 degrees C and below), is enhanced using a thin layer of high-kappa dielectric at the bonding interface. Before bonding, various thin (similar to 5 nm) capping layers of high-kappa dielectrics (Al2O3, HfO2, and TiO2) are deposited separately on polished PE-TEOS wafers, followed by surface activation. After a 300 degrees C anneal in N-2 ambient for 3 h, the bond strength of wafer pairs bonded with PE-TEOS oxide is enhanced by 97.9, 73.3, and 31.0%, respectively, with TiO2, Al2O3, and HfO2 layers at the interface.
Keywords:aluminium compounds;dielectric materials;hafnium compounds;high-k dielectric thin films;plasma materials processing;surface energy;titanium compounds;wafer bonding