Inorganic Chemistry, Vol.48, No.23, 10895-10897, 2009
A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge4O10F2 Clusters and {In2O6} Dimers
A novel layered indate-germanate InGe2O5F(dap) center dot 2H(2)O (1, dap = 1,2-diaminopropane) has been hydrothermally synthesized and structurally characterized. Its structure consists of Ge4O10F2 clusters and In2O6 dimers, which are interconnected to form 4- and 6-ring layers. 1 displays luminescent emission at 422 nm.