Journal of Applied Polymer Science, Vol.110, No.4, 2337-2344, 2008
Preparation and Characterization of Tapioca Starch-Poly(lactic acid)-Cloisite NA(+) Nanocomposite Foams
Tapioca starch, poly(lactic acid), and Cloisite NA(+) nanocomposite foams, with four clay contents (1, 3, 5, 7, wt %), were prepared by melt-intercalation method. Selected structural, thermal, physical, and mechanical properties were characterized using X-ray diffraction (XRD), scanning electron microscopy, differential scanning calorimetry, and an Instron universal testing machine, respectively. XRD results indicated that the 1 wt % nanocomposite foam did not show the characteristic basal reflection of the nanoclay. The 3, 5, and 7 wt % nanocomposite foams produced a mixture of intercalated and tactoid structures. The d(001)-spacing of 3, 5, 7 wt % nanocomposite foams produced increases of 11.40, 11.15, and 10.67 angstrom, respectively, compared to that of the pristine clay. The morphological study showed that the nanocomposite foams exhibited a noticeably reduced cell size, more compact cells, and increased cell density. Increasing clay content caused a decrease in melting temperature (T-m). Bulk spring index and bulk compressibility were influenced (P < 0.05) significantly with the addition of different amounts of clay. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 2337-2344, 2008