Carbon tolerant Ni/YSZ anode modified with 1% (atomic ratio) Au with respect to Ni was tested under methane rich steam reforming conditions. The electrode was proved to be highly tolerant to C deposits, even at methane to water ratios as high as 3, at temperatures ranging between 973-1173 K. The NiAu anode was prepared by in situ combustion synthesis at 873 K and sintered in air at 1123 K. The SEM images have shown that the An modified Ni/YSZ electrode was nancistructured with particle size ranging between 50-100 nm. (c) 2008 Elsevier Inc. All rights reserved.