Journal of Chemical Thermodynamics, Vol.41, No.4, 564-568, 2009
Temperature dependence on mutual solubility of binary (methanol plus limonene) mixture and (liquid plus liquid) equilibria of ternary (methanol plus ethanol plus limonene) mixture
Mutual solubility data of the binary (methanol + limonene) mixture at the temperatures ranging from 288.15 K close to upper critical solution temperature, and ternary (liquid + liquid) equilibrium (tie-lines) of the (methanol + ethanol + limonene) mixture at the temperatures (288.15, 298.15, and 308.15) K have been obtained. The experimental results have been represented accurately in terms of the extended and modified UNIQUAC models with binary parameters, compared with the UNIQUAC model. The temperature dependence of binary and ternary (liquid + liquid) equilibrium for the binary (methanol + limonene) and ternary (methanol + ethanol + limonene) mixtures could be calculated successfully using the extended and modified UNIQUAC model. (C) 2008 Elsevier Ltd. All rights reserved.