Journal of Crystal Growth, Vol.310, No.14, 3366-3371, 2008
Microstructure evolution of peritectic Nd14Fe79B7 alloy during directional solidification
Bridgman type directional solidification experiments were carried out in Nd14Fe79B7 alloy. Microstructure evolutions along with growth velocities were investigated. At low velocities from 1 to 200 mu m/s, the microstructures consisted of leading alpha-Fe dendrites and peritectic Nd2Fe14B phase in the interdendritic region. At medium velocities of 425 and 500 mu m/s, an incomplete banded structure formed, containing circles of alpha-Fe/Nd2Fe14B-Nd2Fe14B dendrites. At high velocities of 1, 3 and 5 mm/s, a transition from gamma-Fe dendrites to Nd2Fe14B dendrites occurred. Phase selection phenomena were theoretically studied using the extremum criterion which assumes growth-controlled phase selection. The theoretical results are in agreement with experimental results at low velocities of 1-200 mu m/s and high velocities of 3 and 5 mm/s. The incomplete dendritic bands at 425 and 500 mu m/s were explained by nucleation of Nd2Fe14B phase at the gamma-Fe dendritic interface, and growth competition between gamma-Fe and the nucleated Nd2Fe14B phase. Phase transition from gamma-Fe to Nd2Fe14B at 1 mm/s was interpreted by abundant nucleation and quick growth of Nd2Fe14B phase at the gamma-Fe dendritic interface. (C) 2008 Elsevier B.V. All rights reserved.
Keywords:directional solidification;morphological stability;nucleation;peritectic;Bridgman technique;rare earth compounds