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Journal of Crystal Growth, Vol.312, No.1, 1-9, 2009
Influence of growth temperature on GaN:Cr incorporation and structural properties in MOVPE
The influence of the growth temperature in metal organic vapor-phase epitaxy (MOVPE) on intentional Cr incorporation during GaN growth is studied in the range 900-1125 degrees C. The structural properties are investigated and compared to those obtained from undoped layers deposited at the same growth conditions and using the same growth procedure: Whereas, the best surface morphology and the best crystal quality are found at 1125 degrees C for undoped GaN layers, the best structural and morphological properties are obtained for the Cr-doped GaN (GaN:Cr) layers grown at 950 degrees C. GaN:Cr layers deposited at this temperature additionally exhibit the highest Cr concentration in the series as well as a Cr accumulation in the beginning stage of GaN:Cr growth. The accumulation may be responsible for the changed growth mode and the improved structural characteristics as well as for the observed V-shaped defects usually associated with strain relaxation. Thermo-remanent magnetization and a hysteresis loop were observed even above room temperature. The magnetic properties correlate to the structural properties of GaN:Cr layers. (C) 2009 Elsevier B.V. All rights reserved.
Keywords:Crystallites;Metalorganic vapor phase epitaxy;Nitrides;Magnetic materials;Semiconducting materials