Journal of Hazardous Materials, Vol.161, No.2-3, 649-656, 2009
Adsorption studies of molasse's wastewaters on activated carbon: Modelling with a new fractal kinetic equation and evaluation of kinetic models
Adsorption kinetic of molasses wastewaters after anaerobic digestion (MSWD) and melanoidin respectively on activated carbon was studied at different pH. The kinetic parameters could be determined using classical kinetic equations and a recently published fractal kinetic equation. A linear form of this equation can also be used to fit adsorption data. Even with lower correlation coefficients the fractal kinetic equation gives lower normalized standard deviation values than the pseudo-second order model generally used to fit adsorption kinetic data, indicating that the fractal kinetic model is much more accurate for describing the kinetic adsorption data than the pseudo-second order kinetic model. (C) 2008 Elsevier B.V. All rights reserved.
Keywords:Activated carbon;Fractal kinetic equation;Molasses spentwash;Melanoidin;Pseudo-second order kinetic model