화학공학소재연구정보센터
Journal of Materials Science, Vol.44, No.8, 2128-2136, 2009
Oxidation behavior of green coke-based carbon-ceramic composites incorporating micro- and nano-silicon carbide
The oxidation resistance of the carbon-ceramic composites developed using green coke-based carbon and carbon black as carbon source, boron carbide, and micro- and nano-silicon carbide was carried out in the temperature range of 800 to 1,200 A degrees C. Silicon carbide particulate as such and silicon carbide obtained by the reaction of green coke and silicon provided micro silicon carbide while silicon and carbon black and sol-gel silica and carbon black used as silicon carbide precursors led to the formation of nano-silicon carbide. The oxidation resistance of these composites at 800 to 1,200 A degrees C for 10 h showed that the size of the silicon carbide influenced the oxidation resistance. The weight gain due to protective coating formed on oxidation was higher in composites containing nano-silicon carbide as compared to the composites containing micro silicon carbide.