화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.112, No.40, 9615-9618, 2008
The A and B terms of magnetic circular dichroism revisited
The temperature-independent part of the magnetic circular dichroism spectrum is conventionally divided into the Faraday A and B terms, where the A term is nonzero only for systems with degenerate states. We propose that this separation is abandoned in favor of a unified temperature-independent term. This proposal is based on complex polarization propagator calculations on three structurally similar porphyrins. These calculations also suggest that the Soret band of Zn-porphyrin is determined by an isolated degenerate 2E(u) state.