화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.113, No.16, 4110-4116, 2009
High-Precision Calculations of the Hyperfine Constants for the Low-Lying Excited S-2 States of Be+
High-precision Hylleraas-type calculations of the hyperfine constants for the four lowest excited 3 S-2, 4 S-2, 5 S-2, and 6 S-2 states of the Be-9(+) ion are reported. Small adjustments to the hyperfine constants arising from effects that include the finite nuclear mass, the magnetization density distribution over the nucleus, the Breit-Rosenthal correction for finite nuclear size, and lowest-order relativistic and quantum electrodynamic corrections are considered. The final values obtained for the hyperfine constants for the n S-2 states were: -158.78, -62.43, -30.66, and -17.29 MHz for n = 3, 4, 5, and 6, respectively.