화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.113, No.26, 7244-7252, 2009
Statistics of Indistinguishable Particles
The wave function of a system containing identical particles takes into account the relationship between a particle's intrinsic spin and its statistical property. Specifically, the exchange of two identical particles having odd-half-integer spin results in the wave function changing sign, whereas the exchange of two identical particles having integer spin is accompanied by no such sign change. This is embodied in a term (-1)(2s), which has the value +1 for integer s (bosons), and -1 for odd-half-integer s (fermions), where s is the particle spin. All of this is well-known. In the nonrelativistic limit, a detailed consideration of the exchange of two identical particles shows that exchange is accompanied by a 2 pi reorientation that yields the (-1)(2s) term. The same bookkeeping is applicable to the relativistic case described by the proper orthochronous Lorentz group, because any proper orthochronous Lorentz transformation can be expressed as the product of spatial rotations and a boost along the direction of motion.