화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.113, No.1, 239-244, 2009
Phase Behavior and Microstructure of Microemulsions Containing the Hydrophobic Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate
The phase behavior and microstructure of the ternary system water/1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6))/Triton X-100 was studied as a function of temperature and ionic liquid (IL) mass fraction a. In the present study, a hydrophobic IL instead of commonly used organic solvents such as n-alkanes is used. The fish-shaped region is distorted at low and high values of alpha, whereas it is symmetric at intermediate alpha. With increasing alpha, the extension of the three-phase region decreases regarding the surfactant concentration range, whereas it increases regarding the temperature range. For comparison the phase behavior of two ternary water/bmimPF(6)/alkyl oligoethyleneoxide (CiEj) systems has been investigated. Our results are compared with those obtained for water/n-alkane/CiEj and IL/n-alkane/CiEj systems, respectively.