H-1 MAS solid-state NMR methods are applied to elucidate the conduction mechanism of an anhydrous proton conducting triazole-functionalized polysiloxane. At temperatures below T= 260 K, hydrogen bonding between neighboring heterocycles is observed and a dimer formation can be excluded. From the temperature dependence of H-1 MAS NMR spectra, different dynamic processes of the triazole ring contributing to the proton conduction process are qualitatively and quantitatively analyzed and detailed insight into the conduction mechanism and temperature-dependent structural changes is obtained. Although the dynamics processes oil the molecular level are qualitatively in good agreement with the findings from macroscopic conductivity measurements, temperature-dependent factors oil mesoscopic scales beyond the local molecular mobility influence the macroscopic Conductivity and hamper quantitative interpretation.