To investigate the applicability of high nitrogen (HN) austenitic stainless steel as bipolar plates for proton exchange membrane fuel cells (PEFCs), the polarization tests were carried out in synthetic solutions (0.05 M SO42- (pHs 2.3, 4.3 and 5.5) +2 ppm F-) at 353 K. Interfacial contact resistance between the stain-less steel and gas diffusion layer was measured before and after polarization. A single cell employing the HN stainless steel as bipolar plates was operated for 1000 h at 0.5 A cm(-2) (12.5 A). The single cell exhibited voltage drop of 17 mV during the operation. Corrosion products were scarcely detected for the HN stainless steel bipolar plate, as confirmed by scanning electron microscopy. After the polarization tests and single cell operation, XPS analyses were carried out to examine the resulting Surface states. In the synthetic solutions to pH 4.3. the passive films mainly consisted of oxides enriched with Cr. When the solution pH was 5.5. on the other hand, the films were mainly composed of Fe-oxides. After the single cell operation for 1000h, it was found that the passive films of the rib surface for the gas inlet part Was mainly composed by Fe-oxides. On the other hand, the passive films for the ribs from center to gas outlet part were mainly made up of Cr-oxides. By combining the simulated and real operation environments, it is believed that the corrosion resistive Cr-oxides passive layer of the FIN stainless steel obtained by the presence of nitrogen incorporated into the stainless steel could contribute to the maintenance of the higher cell voltage during the extensive cell operation. (C) 2008 Elsevier B.V. All rights reserved.