Whereas Ce0.9Sr0.1Cr0.5V0.5O3 is an active fuel cell anode catalyst for conversion of only the H2S content of 0.5% H2S-CH4 at 850 degrees C, inclusion of 5 wt% NiO to form a composite catalyst enabled concurrent electrochemical conversion of CH4. A fuel cell with a 0.3 mm thick YSZ membrane and Ce0.9Sr0.1Cr0.5V0.5O3 as anode catalyst had a maximum power density of 85 mWcm(-2) in 0.5% H2S-CH4 at 850 degrees C, arising only from the electro-oxidation of H2S. Using a same thick membrane, promotion of the anode with 5 wt% NiO increased the total anode electro-oxidation activity to afford maximum power density of 100 mW cm(-2) in 0.5% H2S-CH4. The same membrane provided 30 mWcm(-2) in pure CH4, showing that the incremental improvement arose substantially from CH4 Conversion. Performance of each anode was stable for over 12 h at maximum power output. XPS and XRD analyses showed that an increase in conductivity of Ce0.9Sr0.1Cr0.5V0.5O3 in H2S-containing environments resulted from a change in composition and structure from the tetragonal oxide to monoclinic Ce0.9Sr0.1Cr0.5V0.5O3. (C) 2009 Elsevier B.V. All rights reserved.