Journal of Rheology, Vol.52, No.5, 1113-1129, 2008
A study of the nonlinear rheology of complex fluids using diffusing wave spectroscopy
Diffusing wave spectroscopy's (DWS) sensitivity to local shear rate has been used to investigate the nonlinear rheology of (1) a doped shear thinning, semidilute polymer solution measured in the cone-plate and parallel-plate geometries and of (2) doped shear banding wormlike micelles solutions measured in the cylindrical-Couette geometry. DWS measurements of the semidilute polymer solution in the cone-plate geometry under stress controlled conditions were used to construct a flow curve for the material, the expected radial dependence of the local shear rate being demonstrated in the parallel-plate geometry. The method is shown to be sensitive to shear banding in semidilute wormlike micelles in the cylindrical-Couette geometry under strain controlled conditions, and DWS correlation functions were quantitatively interpreted using a heterogeneous shear flow model. Flow curves and shear rate profiles were inferred from these measurements. (C) 2008 The Society of Rheology.