화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.92, No.2, 311-317, 2009
Low-Temperature Densification of TiN-TiB2 Composites Through Reactive Hot Pressing with Excess Ti Additions
Reactive hot pressing of Ti and BN powder mixtures is used to produce dense TiNx-TiB2 composites. The effect of excess Ti along with a small addition, similar to 1 wt% Ni, on the reaction and densification of the composite was investigated. A composite of similar to 99.9% relative density (RD) was produced at 1200 degrees C at 40 MPa for 30 min with 1 wt% Ni, whereas composites produced without Ni are porous and contain residual reactants. The microstructural studies on composite samples with excess Ti produced at short durations indicate the presence of a transient (Ni-Ti) phase from which Ti is finally removed to form substoichiometric TiNx. The hardness of the dense TiNx-TiB2 composite is similar to 22 GPa. The densification mechanism in this system is contrasted with the role of nonstoichiometry in the Zr-B4C system.