화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.92, No.7, 1384-1390, 2009
Particle Rearrangement and Pore Space Coarsening During Solid-State Sintering
Coarsening of porosity during sintering has been observed in powder compacts of metallic, ceramic, and amorphous materials. Monitoring and modelling of the growth of individual (closed) pores in the late sintering stages are well established. Porosity is interconnected up to very high densities. Coarsening of the continuous pore space takes place during the initial and intermediate sintering stages. This coarsening is caused by localized transport of atoms or molecules (diffusion or viscous flow) as well as by bulk particle movement (rearrangement). Its quantitative exploration poses problems both experimentally and theoretically. Ways to characterize the geometry of the interconnected pore space and of closed pores are discussed with emphasis on stereological parameters. Recent and classical approaches, experimental findings with 2D model arrangements (as the formation and opening up of particle contacts, pore coarsening, and particle rearrangement) and some advances of computer simulations are discussed together with open questions.