Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SIW10O36](8-): A totally inorganic oxygen-evolving catalyst

Sartorel A; Carraro M; Scorrano G; De Zorzi R; Geremia S; McDaniel ND; Bernhard S; Bonchio M

Journal of the American Chemical Society, Vol.130, No.15, 5006-5006, 2008

Sartorel A, Carraro M, Scorrano G, De Zorzi R, Geremia S, McDaniel ND, Bernhard S, Bonchio M

Solid state and solution evidence confirms the embedding of an adamantane like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h(-1).

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