화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.130, No.22, 6894-6894, 2008
Synthesis and structure of a hexacoordinate carbon compound
In an exploration of six coordination and hypervalence in carbon compounds, steric constraints have been employed to bring four ether O atoms in close proximity to an allenic carbon atom. The dimethylated dication 2 is confirmed to have hexacoordinate carbon by experimental charge density analysis and DFT calculations and is arguably hypervalent.