Journal of the American Chemical Society, Vol.130, No.39, 12878-12878, 2008
A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release
Starting from RuHCl(H-2)(PCy3)(2), a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.