Journal of the American Chemical Society, Vol.130, No.45, 14972-14972, 2008
Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles
Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.