Journal of the American Chemical Society, Vol.131, No.9, 3168-3168, 2009
A Neutral Ga-6 Octahedron: Synthesis, Structure, and Aromaticity
Potassium graphite reduction of L:Ga(Mes)Cl-2 [L: = :C{(i-Pr)NC(Me)}(2), Mes = 2,4,6-Me3C6H2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl)(Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga-6 octahedron L:Ga[Ga(4)Mes(4)]Ga:L (3).