화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.131, No.18, 6328-6328, 2009
Effective Transition Probability for the Faraday Effect of Lanthanide(III) Ion Solutions
The Faraday effects of 14 lanthanide(III) ion solutions were systematically analyzed on the basis of the Faraday C term. The effective transition probability, K, which measures the magneto-optical contribution of the 4f(n) -> 4f(n-1)5d transition to the molar Verdet constant, was determined. Linear correlations between K and the square root of the molar magnetic susceptibility of the lanthanide(III) ions, x(m)(1/2), were obtained. From the observed new regularity, K for promethium(III) was estimated.