Application of cyclophosphazene derivatives as flame retardants for ABS

Young Jae Shin; Young Rok Ham; Sun Hee Kim; Dae Hee Lee; Sang Beom Kim; Chul Soon Park; Young Mi Yoo; Jin Gon Kim; Soo Han Kwon; Jae Sup Shin

Journal of Industrial and Engineering Chemistry, Vol.16, No.3, 364-367, May, 2010

DOI10.1016/j.jiec.2009.08.001 Export Citation

Application of cyclophosphazene derivatives as flame retardants for ABS

Young Jae Shin, Young Rok Ham¹, Sun Hee Kim¹, Dae Hee Lee², Sang Beom Kim², Chul Soon Park¹, Young Mi Yoo¹, Jin Gon Kim¹, Soo Han Kwon¹, and Jae Sup Shin^{1, †}

Department of Electrical and Computer Engineering, Texas A&M University, College Station, TX 77843, USA
¹Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea
²Doobon Inc., Cheongwon, Chungbuk 363-893, Republic of Korea

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Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP.

Keywords:Flame retardant;Cyclotriphosphazene;ABS

[References]

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Khasbaatar AD, Chun YJ, Choi US, J. Ind. Eng. Chem., 13(7), 1109 (2007)
Kim JS, Choi US, Ko YG, Kim SH, J. Ind. Eng. Chem., 8(3), 218 (2002)
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Kumar D, Gupta AD, Khullar M, J. Polym. Sci.: Polym. Chem. Ed., 31, 707 (1993)
Ding J, Shi W, Polym. Degrad. Stabil., 84, 159 (2004)
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Wu Q, Lu J, Qu B, Polym. Int., 52, 1326 (2003)
Allcock HR, Chem. Mater., 6, 1476 (1994)
Levchik SV, Camino G, Luda MP, Costa L, Lindsay A, Stevenson D, J. Appl. Polym. Sci., 67(3), 461 (1998)
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Levchik SV, Levchik GF, Balabanovich AI, Weil ED, Klatt M, Angew. Macromol. Chem., 264, 48 (1999)
Allcock HR, Phosphorus.Nitrogen Compounds, Academic Press, New York (1972)
Zhu WM, Weil ED, Mukhopadhyay S, J. Appl. Polym. Sci., 62(13), 2267 (1996)
Levchik SV, Levchik GF, Camino G, Costa L, Lesnikovich AI, Fire Mater., 20, 183 (1996)
Allcock HR, Walsh EJ, J. Am. Chem. Soc., 94, 4538 (1972)
Kim HY, Shin YJ, Ji YJ, Shin JS, J. Korean Ind. Eng. Chem., 17, 141 (2006)
Allcock HR, J. Am. Chem. Soc., 86, 2591 (1964)
Allcock HR, Best RJ, Can. J. Chem., 42, 447 (1964)
Allcock HR, Kuggel RL, Inorg. Chem., 5, 1016 (1966)
Sorenson WR, Campbell TW, Preparative Methods of Polymer Chemistry, Wiley, New York (2001)

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[1] Peng HQ, Zhou Q, Wang DY, Chen L, Wang YZ, J. Ind. Eng. Chem., 14(5), 589 (2008)

[2] Choi YS, Choi SK, Moon SC, Jo BW, J. Ind. Eng. Chem., 14(3), 387 (2008)

[3] Khasbaatar AD, Chun YJ, Choi US, J. Ind. Eng. Chem., 13(7), 1109 (2007)

[4] Kim JS, Choi US, Ko YG, Kim SH, J. Ind. Eng. Chem., 8(3), 218 (2002)

[5] Ko YG, Choi US, Ahn DJ, Kim JS, Kim TY, J. Ind. Eng. Chem., 7(2), 72 (2001)

[6] Potin P, Jaeger RD, Eur. Polym. J., 27, 341 (1991)

[7] Kumar D, Gupta AD, Khullar M, J. Polym. Sci.: Polym. Chem. Ed., 31, 707 (1993)

[8] Ding J, Shi W, Polym. Degrad. Stabil., 84, 159 (2004)

[9] Horacek H, Pieh S, Polym. Int., 49, 1106 (2000)

[10] Wu Q, Lu J, Qu B, Polym. Int., 52, 1326 (2003)

[11] Allcock HR, Chem. Mater., 6, 1476 (1994)

[12] Levchik SV, Camino G, Luda MP, Costa L, Lindsay A, Stevenson D, J. Appl. Polym. Sci., 67(3), 461 (1998)

[13] Weil ED, Patel NG, Fire Mater., 18, 1 (1994)

[14] Levchik SV, Levchik GF, Balabanovich AI, Weil ED, Klatt M, Angew. Macromol. Chem., 264, 48 (1999)

[15] Allcock HR, Phosphorus.Nitrogen Compounds, Academic Press, New York (1972)

[16] Zhu WM, Weil ED, Mukhopadhyay S, J. Appl. Polym. Sci., 62(13), 2267 (1996)

[17] Levchik SV, Levchik GF, Camino G, Costa L, Lesnikovich AI, Fire Mater., 20, 183 (1996)

[18] Allcock HR, Walsh EJ, J. Am. Chem. Soc., 94, 4538 (1972)

[19] Kim HY, Shin YJ, Ji YJ, Shin JS, J. Korean Ind. Eng. Chem., 17, 141 (2006)

[20] Allcock HR, J. Am. Chem. Soc., 86, 2591 (1964)

[21] Allcock HR, Best RJ, Can. J. Chem., 42, 447 (1964)

[22] Allcock HR, Kuggel RL, Inorg. Chem., 5, 1016 (1966)

[23] Sorenson WR, Campbell TW, Preparative Methods of Polymer Chemistry, Wiley, New York (2001)