화학공학소재연구정보센터
Macromolecules, Vol.41, No.19, 7239-7242, 2008
Self-diffusion in binary blends of cyclic and linear polymers
A lattice model is used to estimate the self-diffusivity of entangled cyclic and linear polymers in blends of varying compositions. To interpret simulation results, we suggest a minimal constraint release model for the motion of a cyclic polymer infiltrated by neighboring linear chains. Both the simulation and recently reported experimental data on entangled DNA solutions support the simple model over a wide range of blend compositions, concentrations, and molecular weights.